111 Silicon nitride(Si3N4 Ceramic)

Si3N4 Ceramic

Silicon nitride ceramics are an inorganic material that does not shrink during sintering. It is made of silicon powder as a raw material. First, the desired shape is made by the usual molding method,  then preliminary azotized in nitrogen under 1200℃, so that a part of the silicon powder reacts with nitrogen to generate silicon nitride, and then a second azotizing in a high temperature furnace of 1350℃ to 1450℃ to react into silicon nitride. Silicon nitride with 99% theoretical density can be made by thermal pressure sintering method. The thermal conductivity of Si3N4 ceramics at room temperature ranges from 10 to 16 W.m-1.K-1.

Silicon nitride (Si3N4) has made great strides in recent years beyond the biomedical industry. R&D has led to the development of a number of industrial applications for silicon nitride-based materials, paving the way to manufacture different types of silicon nitride. These methods of fabrication have governed the resulting properties and applications of silicon nitride, allowing for a great deal of flexibility and customization to create precisely the material needed for an application.


The use of silicon nitride has also been recognized in the field of optics, having great transparency in the spectral range, giving rise to Si3N4 photonics. The broadband nature of Si3N4 has allowed it to be used in biochemical and biomedical optical applications, biophotonics, tele- and data communications, and optical signal processing, sensing from visible through near to mid-infrared wavelengths.


Molecular Formula

Si3N4

Relative Molecular Mass

140.28

Color

Gray, Gray Black

Crystal System

Hexahedral

Preparation Method

Heat Pressing

Relative Density

99.5%

Density

3.2+/-0.02 g/cm3

Moh's Hardness

9~9.5

Melting Point

1900℃ , Usually decomposed at 1900℃ at normal pressure

Thermal Expansivity

2.8~3.2×10-6/℃ (20~1000℃)

Heat Capacity

0.71J/(g·K)

Thermal Conductivity

15~ 20W/(m·K)

Modulus of Elasticity

300~320 GPa

Fracture Toughness

6.0~7.0 MPa.m

Flexural Strength

650~750 Mpa

Webpark Module

10~12

Solubility

Insoluble in water. Solute in hydrofluoric acid

Oxidizing Temperature

The temperature of starting oxidation in the air is 1300 to 1400℃


NULL